期刊
ACS APPLIED MATERIALS & INTERFACES
卷 2, 期 2, 页码 339-342出版社
AMER CHEMICAL SOC
DOI: 10.1021/am9007243
关键词
mercury(II) ion; mercury-specific oligonucleotides; unmodified silver nanoparticles; thymine-Hg2+-thymine coordination; colorimetry
资金
- National Natural Science Foundation of China [20890022]
- National Key Basic Research Development Project of China [2010CB933602]
- Project of Chinese Academy of Sciences [KJCX2-YW-H09]
A sensitive and selective colorimetric detection method for mercury(II) has been well-estabilished in this paper. It was based on the conformation change of mercury-specific oligonucleotides (MSO) from random coil structure to hairpin structure upon the addition of Hg2+ and the phenomenon of salt-induced unmodified silver nanoparticles (AgNPs) aggregation. The calibration curve showed that the net absorption ratio value at 395 and 570 nm increased linearly over the Hg2+ concentration range of 25-500 nM with a limit of detection of 17 nM. The other environmentally relevant metal ions did not interfere with the determination of Hg2+.
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