期刊
ACS APPLIED MATERIALS & INTERFACES
卷 1, 期 5, 页码 1045-1052出版社
AMER CHEMICAL SOC
DOI: 10.1021/am900023j
关键词
magnesium alloy; ionic liquids; surface film; NMR; corrosion
资金
- EPSRC
- Australian Research Council
- Australian Centre For Electromaterials Science
- Australian Postgraduate Award
- EPSRC [EP/F022913/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F022913/1] Funding Source: researchfish
Ionic liquids (ILs) based on trihexyltetradecylphosphonium coupled with either diphenylphosphate or bis(trifluoromethanesulfonyl)amide have been shown to react with magnesium alloy surfaces, leading to the formation a surface film that can improve the corrosion resistance of the alloy. The morphology and microstructure of the magnesium surface seems critical in determining the nature of the interphase, with grain boundary phases and intermetallics within the grain, rich in zirconium and zinc, showing almost no interaction with the IL and thereby resulting in a heterogeneous surface film. This has been explained, on the basis of solid-state NMR evidence, as being due to the extremely low reactivity of the native oxide films on the intermetallics (ZrO2 and ZnO) with the IL as compared with the magnesium-rich matrix where a magnesium hydroxide and/or carbonate inorganic surface is likely. Solid-state NMR characterization of the ZE41 alloy surface treated with the IL based on (Tf)(2)N- indicates that this anion reacts to form a metal fluoride rich surface in addition to an organic component. The diphenylphosphate anion also seems to undergo an additional chemical process on the metal surface, indicating that him formation on the metal is not a simple chemical interaction between the components of the IL and the substrate but may involve electrochemical processes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据