期刊
ACS APPLIED MATERIALS & INTERFACES
卷 1, 期 7, 页码 1533-1538出版社
AMER CHEMICAL SOC
DOI: 10.1021/am9001953
关键词
gold nanoparticles; DTNBA; colorimetric; ion detection; chromium
资金
- NSFC [20773051]
- Major State Basic Research Development Program [2007CB808006]
- Programs for New Century Excellent Talents in University (NCET)
- 111 project [B06009]
A simply prepared gold nanoparticle-based sensor, 5,5'-dithiobis(2-nitrobenzoic acid) (DTNBA)-modified gold nanoparticles, was prepared to explore the sensitive and selective detection of metal ions using a colorimetric technique. The selective detection of trace levels (93.6 ppb) Cr3+ in aqueous solution was achieved over 15 other metal ions. The functionalized gold nanoparticles became aggregated in solution in the presence of Cr3+ by an ion-templated chelation process, which caused an easily measurable change in the extinction spectrum of the particles and provided an inherently sensitive method for Cr3+ detection in aqueous solution.
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