期刊
ACS APPLIED MATERIALS & INTERFACES
卷 2, 期 1, 页码 127-133出版社
AMER CHEMICAL SOC
DOI: 10.1021/am900622p
关键词
hollow microspheres; Pd nanoparticles; microcapsule; chlorophenols; hydrodechlorination
资金
- National Science Foundation of China [20974051]
- Tianjin Natural Science Foundation [09JCYBJC02800]
- Program For New Century Excellent Talents in University [NCET-06-0216]
A microreactor of Pd nanoparticles immobilized shell-corona hollow microspheres of poly[styrene-co-2-(acetoacetoxy) ethyl methacrylate-co-acrylamide] has been designed for catalytic hydrodechlorination (HDC) of chlorophenols in the sole solvent of water. The strategy of the combined use of the shell-corona hollow microspheres as microcapsule and catalyst scaffold endues the microreactor several advantages. First, the microreactor can be dispersed in the sole solvent of water and acts as a quasi-homogeneous catalyst for catalytic HDC of chlorophenols. Second, the reactant of chlorophenols can be highly concentrated within the hollow microspheres of the microreactor in the sole solvent of water. Third, the resultant product of phenol can be favorably excreted off the microreactor into water because of the polar difference between the reactant of chlorophenols and the product of phenol. Ascribed to the combined advantages, catalytic HDC of chlorophenols can be performed efficiently within the microreactor in the sole solvent of water at room temperature under atmosphere pressure.
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