期刊
NATURE ENERGY
卷 3, 期 8, 页码 682-+出版社
NATURE PORTFOLIO
DOI: 10.1038/s41560-018-0200-6
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资金
- Korea Research Institute of Chemical Technology (KRICT), Republic of Korea [KK1802-A01]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade Industry AMP
- Energy (MOTIE) of the Republic of Korea [20163010012470]
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT AMP
- Future Planning (MSIP) of Korea [NRF-2016M3A6A7945503]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2015R1A6A3A04058164]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20163010012470] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2016M3A6A7945503, 2015R1A6A3A04058164] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Perovskite solar cells (PSCs) require both high efficiency and good long-term stability if they are to be commercialized. It is crucial to finely optimize the energy level matching between the perovskites and hole-transporting materials to achieve better performance. Here, we synthesize a fluorene-terminated hole-transporting material with a fine-tuned energy level and a high glass transition temperature to ensure highly efficient and thermally stable PSCs. We use this material to fabricate photovoltaic devices with 23.2% efficiency (under reverse scanning) with a steady-state efficiency of 22.85% for small-area (-0.094 cm(2)) cells and 21.7% efficiency (under reverse scanning) for large-area (-1 cm(2)) cells. We also achieve certified efficiencies of 22.6% (small-area cells, -0.094 cm(2)) and 20.9% (large-area, -1 cm(2)). The resultant device shows better thermal stability than the device with spiro-OMeTAD, maintaining almost 95% of its initial performance for more than 500 h after thermal annealing at 60 degrees C.
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