期刊
CHEMISTRYSELECT
卷 3, 期 18, 页码 5143-5146出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201800588
关键词
Aziridination; Copper; Nitrene; Olefin
资金
- Mississippi State University, Department of Chemistry
Aziridines are valued as important building blocks for the synthesis of a wide range of active compounds. The development of efficient, cost effective catalysts for nitrene transfer reactions to olefins is a continuing area of research in modern chemistry. There are a number of transition metal complexes that are known to catalyse the aziridination of olefins, however most require expensive transition metal ions. Herein we report our efforts to generate aziridines using a copper(II) complex that offers high efficiency at forming aziridines from olefins and N-transfer agents.
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