4.4 Article

A High-Performance Flexible Supercapacitor Anode Based On Polyaniline/Fe3O4 Composite@Carbon Cloth

期刊

CHEMISTRYSELECT
卷 3, 期 11, 页码 3234-3240

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201800305

关键词

anode material; carbon cloth; cycling stability; Fe3O4; PANI/Fe3O4; specific capacitance; supercapacitor

资金

  1. Ramanujan Fellowship, Department of Science and Technology (DST), Govt. of India
  2. CSIR-NIIST Thiruvananthapuram, India

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Herein, we report for the first time, the synthesis of a binder-free flexible Polyaniline (PANI) and Iron Oxide (Fe3O4) nanocomposite (PANI/Fe3O4) electrode by the direct growth of active materials over carbon cloth. The carbon cloth substrate, with its three-dimensional porous structure, provides more electrolyte accessibility and acts as an effective conductive pathway for efficient electrical transport between the active materials and the current collector. The PANI/Fe3O4 nanocomposite electrode exhibits a maximum specific capacitance of 365 F g(-1) in a stable potential window ranging from -1V to 0V. Also it retains a cycling stability of 91% even after 4000 charge-discharge cycles at a constant current density of 5A g(-1). These results indicate that PANI/Fe3O4 nanocomposite electrode has a significant potential as an inexpensive anode for future electrochemical energy storage systems.

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