4.7 Article

PbCrO4 yellow-pigment nanorods: An efficient and stable visible-light-active photocatalyst for O2 evolution and photodegradation

期刊

SCIENCE CHINA-MATERIALS
卷 61, 期 8, 页码 1033-1039

出版社

SCIENCE PRESS
DOI: 10.1007/s40843-017-9229-x

关键词

O-2 evolution; pollutant; PbCrO4 nanorods; visible-light-active; photocatalyst

资金

  1. National Natural Science Foundation of China [21401190]
  2. Science and Technology Project of Research Foundation of China Postdoctoral Science [2017M612710, 2016M592519]
  3. Shenzhen Peacock Plan [827-000059, 827-000113, KQTD2016053112042971]
  4. Science and Technology Planning Project of Guangdong Province [2016B050501005]
  5. Educational Commission of Guangdong Province [2016KCXTD006, 2016KSTCX126]

向作者/读者索取更多资源

Here, PbCrO4 nanorods, a commonly used and low-cost yellow pigment, was synthesized via a simple precipitation reaction and can serve as a highly efficient oxygen production and photodegradation photocatalyst. The obtained PbCrO4 nanorods exhibit excellent stability and photocatalytic performance for O-2 evolution from water. The production rate is approximately 314.0 mu mol h(-1) g(-1) under visible light, and the quantum efficiency is approximately 2.16% at 420 +/- 10 nm and 0.05% at 600 +/- 10 nm. In addition, the PbCrO4 shows good degradation performance for methylene blue, methyl blue, methyl orange and phenol under visible-light irradiation. These results indicate that it is potential to fabricate an effective, robust PbCrO4 photocatalyst by transforming heavy-metal pollutants Pb(II) and Cr(VI) into a highly efficient O-2 evolution and photodegradation material. This strategy which uses pollutant to produce clean energy and degrade contaminants is completely green and environmentally benign, and thus could be a promising way for practical environmental applications.

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