期刊
ACS CENTRAL SCIENCE
卷 4, 期 4, 页码 440-450出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscentsci.8b00073
关键词
-
资金
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
- U.S. Department of Energy, Office of Fossil Energy, National Energy Technology Laboratory [DE-FE0026472]
- National Science Foundation Small Bussiness Innovation Research (NSF-SBIR) [1632486]
- Robert A. Welch Foundation through a Welch Endowed Chair [A-0030]
- National Science Foundation Graduate Research Fellowship [DGE: 1252521]
- Dow Chemical Graduate Fellowship
Group 4 metal-based metal-organic frameworks (MIV-MOFs), including Ti-, Zr-, and Hf-based MOFs, are one of the most attractive classes of MOF materials owing to their superior chemical stability and structural tunability. Despite being a relatively new field, MIV-MOFs have attracted significant research attention in the past few years, leading to exciting advances in syntheses and applications. In this outlook, we start with a brief overview of the history and current status of MIV-MOFs, emphasizing the challenges encountered in their syntheses. The unique properties of MIV-MOFs are discussed, including their high chemical stability and strong tolerance toward defects. Particular emphasis is placed on defect engineering in Zr-MOFs which offers additional routes to tailor their functions. Photocatalysis of MIV-MOF is introduced as a representative example of their emerging applications. Finally, we conclude with the perspective of new opportunities in synthesis and defect engineering.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据