期刊
SCIENCE BULLETIN
卷 63, 期 13, 页码 831-839出版社
SCIENCE PRESS
DOI: 10.1016/j.scib.2018.05.021
关键词
MOF-5; Uranium; Sorption; Interaction mechanism; XPS analysis
资金
- National Key Research and Development Program of China [2017YFA0207002]
- National Natural Science Foundation of China [21577032, 21607042]
- Fundamental Research Funds for the Central Universities [2018ZD11, 2018MS114, 2016MS02]
- Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection
- Priority Academic Program Development of Jiangsu Higher Education Institutions
With the widespread application of radionuclide U-235(VI), it is inevitable that part of U(VI) is released into the natural environment. The potential toxicity and irreversibility impact on the natural environment has become one of the most forefront pollution problems in nuclear energy utilization. In this work, rod-like metal-organic framework (MOF-5) nanomaterial was synthesized by a solvothermal method and applied to efficiently adsorb U(VI) from aqueous solutions. The batch experimental results showed that the sorption of U(VI) on MOF-5 was strongly dependent on pH and independent of ionic strength, indicating that the dominant interaction mechanism was inner-sphere surface complexation and electrostatic interaction. The maximum sorption capacity of U(VI) on MOF-5 was 237.0 mg/g at pH 5.0 and T = 298 K, and the sorption equilibrium reached within 5 min. The thermodynamic parameters indicated that the removal of U(VI) on MOF-5 was a spontaneous and endothermic process. Additionally, the FT-IR and XPS analyses implied that the high sorption capacity of U(VI) on MOF-5 was mainly attributed to the abundant oxygen-containing functional groups (i.e., C-O and C=O). Such a facile preparation method and efficient removal performance highlighted the application of MOF-5 as a candidate for rapid and efficient radionuclide contamination's elimination in practical applications. (C) 2018 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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