期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 17, 页码 2542-2546出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00390d
关键词
-
资金
- NSF [0955972]
- NNSFC [2137278, 21572163]
- UIUC
A facile formal ene reaction of trisubstituted silylallenes with triplet molecular oxygen involving the cleavage of a H-C(sp(2)) bond has been described. For this formal ene reaction, the silyl substituent was found to be critical to induce peroxide formation. DFT calculations clearly show the dramatic weakening of the allenic C(sp(2))-H bond by the -silyl group.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据