期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 1, 页码 70-74出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00691h
关键词
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资金
- National Natural Science Foundation of China [21372074, 21572053]
A Cu(I)/Ph-Phosferrox complex catalyzed asymmetric Mannich reaction of glycine Schiff bases with isatin-derived ketimines has been described. This strategy can provide direct access to chiral 3-substituted 3-aminooxindoles bearing vicinal quaternary-tertiary carbon stereocenters in high yields (up to 99%), excellent enantioselectivities (up to >99% ee) and moderate to high diastereoselectivities (up to 98 : 2 dr).
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