期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 3, 页码 371-375出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00811b
关键词
-
资金
- National Natural Science Foundation of China [21532001, 21672037]
A three-component reaction of naphthols, sulfur dioxide, and aryldiazonium tetrafluoroborates catalyzed by iron(III) chloride through a radical process via direct C-H functionalization is developed, leading to diverse sulfonated naphthols in good yields. Arylsulfonyl radicals act as the key intermediates during the reaction process, and the presence of iron(III) chloride facilitates the formation of a naphthol radical in the reaction through a single electron transfer. Several sensitive functional groups including nitro, halo, cyano, hydroxy, and ester are all compatible under the conditions.
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