期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 9, 页码 1466-1470出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00125a
关键词
-
资金
- National Basic Research Program of China (973) [2015CB856603]
- Chinese Academy of Sciences [XDB20000000, sioczz201808]
- National Natural Science Foundation of China [20472096, 21372241, 21572052, 20672127, 21421091, 21372250, 21121062, 21302203, 20732008, 21772037, 21772226]
- Fundamental Research Funds for the Central Universities [222201717003]
A facile synthetic method to access 4-amino-isoquinolin-1(2H)-one and oxazole derivatives was disclosed in this paper. The reaction of N-(pivaloyloxy)-amides with ynamides produced 4-amino-isoquinolin-1(2H)-ones in good yields in the presence of (CpRh)-Rh-star(III) catalyst through a C-H bond functionalization. Using Sc(OTf)(3) as the catalyst, oxazole derivatives were obtained in good yields from the same reaction. This protocol features good functional group tolerance and excellent regioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据