期刊
POLYMER REACTION ENGINEERING - 10TH INTERNATIONAL WORKSHOP
卷 302, 期 -, 页码 297-304出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/masy.201000052
关键词
extraction; latex; partitioning; residual monomer; shuttle effect; supercritical carbon dioxide
资金
- Emulsion Polymerization
Extraction of residual monomer from a latex product with supercritical carbon dioxide ((sc)CO2) in a column was studied. Operating conditions were chosen at 35 degrees C and 100 bar. For reducing the residual styrene level in a polystyrene latex from 10(4) ppm to 100 ppm and from 10(4) ppm to 10 ppm, a countercurrent bubble column with latex as continuous and (sc)CO2 as dispersed phase is suggested. Monomer partitioning was demonstrated to be a key parameter in the equipment design. Monomer transport was found to be governed by the shuttle effect, caused by Brownian motion of the latex to and from the H2O/CO2 interface. The drift-flux approach was followed to determine the column flooding conditions. Small column volumes are obtained. (sc)CO2 is a promising extraction medium for residual monomer reduction in latex products. Performance towards steam stripping is better as the final residual monomer level becomes lower.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据