期刊
JOURNAL OF ADVANCED CERAMICS
卷 7, 期 1, 页码 64-71出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s40145-017-0257-x
关键词
ultra-high temperature ceramics (UHTCs); coating; reactive melt infiltration (RMI); alloy
资金
- National Key Research and Development Program of China [2017YFB0703200]
- Science and Technology Commission of Shanghai Municipality [16DZ2260600]
ZrB2-ZrC-SiC ternary coatings on C/C composites are investigated by reactive melt infiltration of ZrSi2 alloy into pre-coatings. Two different pre-coating structures, including porous B4C-C and dense C/B, are designed by slurry dip and chemical vapor deposition (CVD) process respectively. The coating prepared by reactive melt infiltration (RMI) into B4C-C presents a flat and smooth surface with a three-layer cross-sectional structure, namely interior SiC transition layer, gradient ZrB2-ZrC-SiC layer, and ZrB2-ZrC exterior layer. In comparison, the coating prepared by RMI into C/B shows a more granular surface with a different three-layer cross-sectional structure, interior unreacted B-C pre-coating layer, middle SiC layer, and exterior ZrB2-ZrC-ZrSi2 layer. The forming mechanisms of the specific microstructures in two coatings are also investigated and discussed in detail.
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