期刊
CRYSTALS
卷 8, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/cryst8010023
关键词
Prussian Blue analogue; mesoframe; aqueous sodium ion battery
资金
- National Natural Science Foundation of China [21401056, 21473059]
- Large Instruments Open Foundation of East China Normal University
Mesostructure engineering is a potential avenue towards the property control of coordination polymers in addition to the traditional structure design on an atomic/molecular scale. Mesoframes, as a class of mesostructures, have short diffusion pathways for guest species and thus can be an ideal platform for fast storage of guest ions. We report a synthesis of Prussian Blue analogue mesoframes by top-down etching of cubic crystals. Scanning and transmission electron microscopy revealed that the surfaces of the cubic crystals were selectively removed by HCl, leaving the corners, edges, and the cores connected together. The mesoframes were used as a host for the reversible insertion of sodium ions with the help of electrochemistry. The electrochemical intercalation/de-intercalation of Na+ ions in the mesoframes was highly reversible even at a high rate (166.7 C), suggesting that the mesoframes could be a promising cathode material for aqueous sodium ion batteries with excellent rate performance and cycling stability.
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