Nitrogen and hydrogen fractionation in high-mass star-forming cores from observations of HCN and HNC

The ratio between the two stable isotopes of nitrogen, N-14 and N-15, is well measured in the terrestrial atmosphere (similar to 272), and for the pre-solar nebula (similar to 441, deduced from the solar wind). Interestingly, some pristine solar system materials show enrichments in N-15 with respect to the pre-solar nebula value. However, it is not yet clear if and how these enrichments are linked to the past chemical history because we have only a limited number of measurements in dense star-forming regions. In this respect, dense cores, which are believed to be the precursors of clusters and also contain intermediate-and high-mass stars, are important targets because the solar system was probably born within a rich stellar cluster, and such clusters are formed in high-mass star-forming regions. The number of observations in such high-mass dense cores has remained limited so far. In this work, we show the results of IRAM-30 m observations of the J = 1-0 rotational transition of the molecules HCN and HNC and their N-15-bearing counterparts towards 27 intermediate- and high-mass dense cores that are divided almost equally into three evolutionary categories: high-mass starless cores, high-mass protostellar objects, and ultra-compact HII regions. We have also observed the DNC(2-1) rotational transition in order to search for a relation between the isotopic ratios D/H and N-14/N-15. We derive average N-14/N-15 ratios of 359 +/- 16 in HCN and of 438 +/- 21 in HNC, with a dispersion of about 150-200. We find no trend of the N-14/N-15 ratio with evolutionary stage. This result agrees with what has been found for N2H+ and its isotopologues in the same sources, although the N-14/N-15 ratios from N2H+ show a higher dispersion than in HCN/HNC, and on average, their uncertainties are larger as well. Moreover, we have found no correlation between D/H and N-14/N-15 in HNC. These findings indicate that (1) the chemical evolution does not seem to play a role in the fractionation of nitrogen, and that (2) the fractionation of hydrogen and nitrogen in these objects is not related.