期刊
ADVANCED SCIENCE
卷 5, 期 9, 页码 -出版社
WILEY
DOI: 10.1002/advs.201800519
关键词
hybrid structures; reaction dynamics; sodium ion batteries; sodium titanates; synergetic effects
资金
- National Natural Science Foundation of China [21506133]
- Youth Foundation of Sichuan University [2017SCU04A08]
- National Key Research and Development of China [2017YFB0307504, 2016YFD0200404]
- Sichuan University [2017SCU12018, 2018SCU12045]
A novel complementary approach for promising anode materials is proposed. Sodium titanates with layered Na2Ti3O7 and tunnel Na2Ti6O13 hybrid structure are presented, fabricated, and characterized. The hybrid sample exhibits excellent cycling stability and superior rate performance by the inhibition of layered phase transformation and synergetic effect. The structural evolution, reaction mechanism, and reaction dynamics of hybrid electrodes during the sodium insertion/desertion process are carefully investigated. In situ synchrotron X-ray powder diffraction (SXRD) characterization is performed and the result indicates that Na+ inserts into tunnel structure with occurring solid solution reaction and intercalates into Na2Ti3O7 structure with appearing a phase transition in a low voltage. The reaction dynamics reveals that sodium ion diffusion of tunnel Na2Ti6O13 is faster than that of layered Na2Ti3O7. The synergetic complementary properties are significantly conductive to enhance electrochemical behavior of hybrid structure. This study provides a promising candidate anode for advanced sodium ion batteries (SIBs).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据