期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 1, 页码 225-231出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b08334
关键词
polyvinylidene fluoride; silver nanostructures; excimer laser patterning; plasmonic tunability; piezoelectric switching
资金
- GACR [15-19485S, 15-19209S]
- TACR [TH01010997]
A new approach for preparation of active plasmonic component with capability to switch on/off localized surface plasmon resonance (LSPR) by piezoelectric effect is described. Polyvinylidene fluoride (PVDF) was patterned by polarized KrF excimer laser beam. The polarization was perpendicular to polymer orientation introduced during the poling procedure. Consequently the silver nanoclusters were sputtered onto the polymer surface. Application of an external electric field leads to polymer stretching and surface smoothening. Simultaneously, silver clusters are elongated and interconnected; this process leads to dramatic decrease of surface resistance and complete quenching of plasmon related absorption.
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