期刊
ENVIRONMENTAL SCIENCE-NANO
卷 5, 期 4, 页码 1027-1035出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7en01171g
关键词
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资金
- Atlantic Canada Opportunities Agency AIF program
- Nova Scotia Lands Boat Harbor Remediation Program
- Cape Breton University RP program
- Beatrice Hunter Cancer Research Institute (BHCRI)
- Guangdong Province Higher Vocational College & School's Pearl River Scholar Funded Scheme
- NSERC
- BHCRI
Titanium dioxide (TiO2) nanomaterials are extensively used in environmental and energy research. However, their utility is governed by surface interactions with surrounding environments and molecules. A deep understanding of these interactions is critical for the development of advanced TiO2 applications. Herein, we systematically investigate the adsorption of doxorubicin (DOX), a highly toxic chemotherapeutic and model antibiotic pharmaceutical, onto anatase TiO2 nanoparticles and correlate the photodegradation mechanism of DOX with its surface adsorption. Compared to the photodegradation of non-adsorbed species in solution by mobile hydroxyl radicals, the adsorption-dependent surface oxidation by UV-induced holes on TiO2 is more efficient. This study underscores the importance of controlling surface adsorption within photodegradation applications via pH alteration, which would be highly relevant for photo-oxidative remediation of environmental organic pollutants with amine or carbonyl functionalities that chemisorb on titania surfaces.
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