期刊
CHEMELECTROCHEM
卷 5, 期 7, 页码 996-1001出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201701347
关键词
magnesium-ion batteries; molybdenum disulfide; nanosheets; nanofibers; dual-salt electrolytes
资金
- National Natural Science Foundation of China [21431006, 21761132008, 51571184, 21501165]
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China [21521001]
- Key Research Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH036]
- National Basic Research Program of China [2014CB931800]
- Defense Industrial Technology Development Program [JCKY2016208B012]
- CAS [2015HSC-UE007]
In rechargeable Mg batteries, kinetically reasonable and electrolyte-compatible cathode materials are required to achieve high electrochemical performance. Here, we report a high-performance rechargeable Mg battery cathode material that is constructed from layered structural MoS2 nanosheets decorated on conductive nitrogen-doped carbon nanofibers (N-CNFs@MoS2). We demonstrate that N-CNFs@MoS2 exhibits good electrochemical compatibility in two types of dual-salt electrolytes including an all-phenyl complex with lithium chloride (LiCl-APC) and bis(trifluoromethane)sulfonimide lithium salt with magnesium chloride (MgCl2-LiTFSI). The fabricated N-CNFs@MoS2-Mg batteries based on both dual-salt electrolyte systems exhibit good cyclic stability and high rate performance.
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