期刊
CATALYSTS
卷 8, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/catal8070271
关键词
organic bases; C-S bonds; carbon dioxide; benzothiazolones
资金
- Basic Research Plan of Natural Science in Shaanxi Province-General Project (Youth) [2018JQ2030]
- Outstanding Youth Science Fund of Xi'an University of Science and Technology [6310218022]
- Ph.D. Start-up Fund of Xi'an University of Science and Technology [6310117053]
The synthesis of organosulfur compounds via the construction of C-S bonds using CO2 as a C1 resource is very interesting. Herein, a novel method of synthesizing benzothiazolones via the cyclocarbonylation of 2-aminothiophenols with CO2 was developed. A series of organic bases was investigated for the catalysis of cyclocarbonylation, and 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) displayed the best catalytic activity. Then, various reaction parameters such as CO2 pressure, temperature, amount of catalyst, and reaction time for the catalytic performance were studied. Finally, a series of benzothiazolones was synthesized under the optimal reaction conditions, and a possible catalytic mechanism was also proposed.
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