期刊
CATALYSTS
卷 8, 期 4, 页码 -出版社
MDPI
DOI: 10.3390/catal8040164
关键词
dimethyl carbonate; carbon dioxide; ceria nanowires; oxygen vacancy
资金
- National Natural Science Foundation of China [21376276, 21643002]
- Guangdong Province Sci. Tech. Bureau [2017B090901003, 2016B010114004, 2016A050503001]
- Fundamental Research Funds for the Central Universities [171gjc37]
Ultralong 1D CeO2 nanowires were synthesized via an advanced solvothermal method, surface reduced under H-2 atmosphere, and first applied in direct synthesis of dimethyl carbonate (DMC) from CO2 and CH3OH. The micro morphologies, physical parameters of nanowires were fully investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), N-2 adsorption, X-ray photoelectron spectrum (XPS), and temperature-programmed desorption of ammonia/carbon dioxide (NH3-TPD/CO2-TPD). The effects of surface oxygen vacancy and acidic/alkaline sites on the catalytic activity was explored. After reduction, the acidic/alkaline sites of CeO2 nanowires can be dramatically improved and evidently raised the catalytic performance. CeO2 nanowires reduced at 500 degrees C (CeO2_NW_500) exhibited notably superior activity with DMC yield of 16.85 mmol gcat(-1). Furthermore, kinetic insights of initial rate were carried out and the apparent activation energy barrier of CeO2_NW_500 catalyst was found to be 41.9 kJ/mol, much tiny than that of CeO2_NW catalyst (74.7 KJ/mol).
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