期刊
NANO ENERGY
卷 51, 期 -, 页码 128-136出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2018.06.053
关键词
Vanadium nitride; Spatially confined strategy; Supercapacitor; Volumetric capacitance; Cycle life
类别
资金
- National Natural Science Foundation of China [51572100, 61434001]
- HUST Key Interdisciplinary Team Project [2016JCTD101]
- Fundamental Research Funds for the Central Universities [HUST: 2015QN071]
- Wuhan Yellow Crane Talents Program
- City University of Hong Kong Applied Research Grant (ARG) [9667122]
High volumetric capacitance electrode materials are highly desirable for miniaturized and portable capacitive storage devices. Herein, a spatially confined strategy to prepare 0D-in-2D pillared lamellar hybrid comprising vanadium nitride nanodots intercalated carbon nanosheets (VNNDs/CNSs) is proposed for promising capacitive material with high volumetric capacitance. The VNNDs/CNSs shows an ultrahigh volumetric capacitance of 1203.6 F cm(-3) at 1.1 A cm(-3) and rate capability of 703.1 F cm(-3) at 210 A cm(-3) surpassing those of carbon, transition metal oxides/nitrides. Even the 150 mu m-thick film electrode comprising VNNDs/CNSs has a volumetric capacitance of 867.1 F cm(-3). Moreover, the VNNDs/CNSs electrode exhibits extraordinary cycling stability with 90% capacitance retention after 10,000 cycles. The all-solid-state symmetric flexible supercapacitor based on VNNDs/CNSs electrodes boasts a high volumetric energy density/power density of 30.9 Wh L-1/64, 500 W L-1 with 91% capacitance retention after 10000 cycles, rendering promising applications in high-performance flexible supercapacitors. The strategy provides an insight into the rational design of compact, robust and highly conductive electrode materials with high volumetric capacitances and long life.
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