期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 6, 期 30, 页码 8051-8059出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc02243g
关键词
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资金
- IKY Scholarship Programs
- Strengthening Post-Doctoral Research Human Resources Development Program
- Education and Lifelong Learning - European Social Fund - ESF
- Greek government
- Alexander von Humboldt Foundation
Atomic layer deposited hafnium oxide is inserted between the zinc oxide electron transport material and the photoactive blend to serve as an ultra-thin passivation interlayer in organic solar cells with an inverted architecture. The deposition of hafnium oxide significantly improves the surface properties of zinc oxide via effective surface passivation and beneficial modification of surface energy; the latter leads to improved nanomorphology of the photoactive blend. As a result, lower recombination losses and improved electron transport/collection at the cathode interface are achieved. A simultaneous increase in open-circuit voltage, short-circuit current density and fill factor is obtained leading to a power conversion efficiency of 6.30% in the ALD-modified cell using a poly(3-hexylthiophene):indene-C60bisadduct blend as the photoactive layer; this represents a 25% improvement compared to 5.04% of the reference device. Moreover, the incorporation of the passivation interlayer yields a significant stability enhancement in the fabricated solar cells which retain more than 80% of their initial efficiency (T-80 lifetime) after 750 hours while the reference cell exhibits a T-80 equal to 250 hours.
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