期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 6, 期 15, 页码 3937-3944出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc05743a
关键词
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资金
- Key Program of Henan Province for Science and Technology [122300410240, 16A150047]
- National Natural Science Foundation of China [21301158, 21603039, 21373138, NSFC 21771166]
- School Doctor Foundation of Zhengzhou University of Light Industry [2012BSJJ014]
- Outstanding Scholar Program of Henan Province [114200510012]
- Backbone Teacher Project [2014GGJS-081, 2012XGGJS04]
In this study, a visible light-responsive photoelectrochemical (PEC) sensor based on a PPy/Cu2O molecularly imprinted composite film for microcystin-LR (MC-LR) has been fabricated. Uniform Cu2O nanoparticles were electrodeposited on a pretreated indium-doped tin oxide-coated glass (ITO) by carefully controlling the deposition process and used as a photocatalyst to produce photocurrent under visible light. Subsequently, molecularly imprinted polypyrrole (PPy) was modified on the surface of the Cu2O/ITO electrode by an electropolymerization process, which created a certain amount of special recognition sites to enhance the selectivity of the electrode to MC-LR. PEC molecular imprinting sensors were used to rapidly analyze MC-LR concentration by determining changes in photocurrent density. The results showed that the change of photocurrent density was linearly proportional to the logarithm of the MC-LR concentration over the ranges from 1.0 ng L-1 to 100 ng L-1 and from 100 ng L-1 to 10.0 g L-1 with a low detection limit of 0.23 ng L-1 (S/N = 3). Moreover, the PEC sensors exhibited specific selectivity to MC-LR when exposed to certain concentrations of interfering solutions. The constructed PEC sensors demonstrated good applicability in local water systems; this suggested that this promising application of integrating PEC and molecular imprinting technology could be applied to detect other contaminants of emerging concern.
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