4.6 Article

Super-flexible bis(trifluoromethanesulfonyl)-amide doped graphene transparent conductive electrodes for photo-stable perovskite solar cells

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 18, 页码 8251-8258

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta02672f

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资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - the Ministry of Science, ICT & Future Planning [2014R1A5A1009799]
  2. Technology Development Program To Solve Climate Changes through the National Research Foundation of Korea (NRF) - the Ministry of Science, ICT & Future Planning [2015M1A2A2055631]
  3. Global Frontier R&D Program of the Centre for Multi-scale Energy System through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2012M3A6A7054855]
  4. National Research Foundation of Korea [2014R1A5A1009799, 2012M3A6A7054855] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Super-flexible bis(trifluoromethanesulfonyl)-amide (TFSA)-doped graphene transparent conducting electrode (GR TCE)-based FAPbI(3-x)Br(x) perovskite solar cells with 18.9% power conversion efficiency (PCE) for a rigid device and 18.3% for a flexible one are demonstrated because the TFSA-doped GR TCE reveals high conductivity and high transmittance. The unencapsulated TFSA-doped GR TCE-based cell maintained similar to 95% of its initial PCE under a continuous light soaking of 1 Sun at 60 degrees C/30% relative humidity for 1000 h. In addition, the TFSA-doped GR TCE-based flexible perovskite solar cells show excellent bending stabilities, maintaining PCEs of similar to 85, similar to 75, and similar to 35% of their original values after 5000 bending cycles, at R = 12, 8, and 4 mm, respectively.

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