期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 31, 页码 14992-15009出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta04220a
关键词
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资金
- Department of Biotechnology, India [GAP-0378]
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2016R1E1A1A01940995]
- Korean Ministry of the Environment (MOE) [2015001950001]
- CSIR-SRF [31/31(0036)/2017-EMR-I]
Metal-organic frameworks (MOFs) are known to possess many interesting material properties such as high specific surface area, tailorable porosity, adsorption/absorption capabilities, post-synthetic modifications, and chemical/thermal stabilities. Because of these unique features, they have been explored for the development of sensors for a variety of analytes. A large proportion of pre-existing MOF-based sensors are well suited for optical transductions due to a lack of electrical conduction in their pristine forms. Hence, the development of MOF-based electrochemical/electrical sensors requires specialized strategies through which MOFs are modified or hybridized with enhanced conductive moieties (e.g., via doping or post synthetic modification). In this review article, we provide a comprehensive review of various synthetic and integrating strategies to improve electrical conductivity and long-range charge transport properties in MOFs. To this end, we have compiled details of different techniques that have been used to develop electrically/electrochemically active platforms for MOF-based sensing of various targets.
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