期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 27, 页码 13164-13170出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta03799j
关键词
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资金
- National Natural Science Foundation of China [51773165]
- Fundamental Research Fund for the Central Universities
- Young Talent Support Plan of Xi'an Jiaotong University
Sodium titanate (Na2Ti3O7) has been proved to be a potential anode material for sodium-ion batteries. However, its poor rate capability and low electrical conductivity has seriously hindered its application. Therefore, a unique red blood cell-like hollow carbon sphere supported Na2Ti3O7 sodium titanate nanosheet structure (Na2Ti3O7@RHCS) was designed here, which can both improve the electrical conductivity and preserve the structural stability, thus obtaining high rate performance. In addition, the red blood cell-like spherical structure can greatly increase the compacted density via a dense packing mode just like red blood cells stacked together one by one. Meanwhile, the ultrathin nanosheet-like morphology of Na2Ti3O7 could further increase the number of active reaction sites and reduce the diffusion path of sodium ions during the charge-discharge process. This well-designed material exhibits a good cycling performance: a reversible capacity of 110.46 mA h g(-1) at 5C and 45.71 mA h g(-1) at 50C.
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