期刊
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
卷 7, 期 6, 页码 P329-P338出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0181806jss
关键词
-
资金
- Fond Unique Interministeriel [FUI- AAP 19]
The surface chemistry of InAlN ultra-thin layers, having undergone an oxidation procedure usually running through the HEMT fabrication process (850 degrees C, O-2 and O-2+Ar) is studied by XPS. The suitability of XPS analysis to operate as a retro-engineering tool for added value microelectronic devices fabrication is shown. A precise examination of the Al2p, In3d(5/2), Nls, and Ols peaks directly informs about spatial and atomic arrangement. The formation of a covering 3 nm surface oxide is evidenced after O-2 annealing. Once annealed, two specific additional Nls contributions are shown, at higher (404.0 eV) and lower binding energies (397.4 eV) compared to the InAlN matrix one (396.5 eV). To our knowledge, such fingerprint is rather unusual for ternary III-V materials. It reveals the formation of a nitrogen deficient interlayer, situated between the oxide overlayer and the undisturbed matrix, and the presence of interstitial N-2 molecules trapped at the interface. After Ar annealing, both oxide and interface layers are partially reorganized. InAlN reactivity toward higher annealing temperature (950 degrees C) and its stability over time is finally discussed. N-2 molecules are unstable and progressively eliminated in time although nitrogen deficient interlayer still remains. Thermal treatments below 850 degrees C are recommended to preserve the barrier chemical integrity. (C) The Author(s) 2018. Published by ECS.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据