期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 6, 页码 1006-1014出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800146
关键词
asymmetric catalysis; heterocycles; heterofunctionalization; organocatalysis; quaternary stereocenters
资金
- University of Alicante [UAUSTI17-06, VIGROB-173, VIGROB-285, UADIF17-27]
- University of Edinburgh
- Spanish Ministerio de Economia, Industria y Competitividad [CTQ2015-66624-P]
The asymmetric synthesis of 3-substituted oxindoles is a topic of considerable importance because these functionalized heterocycles are found in many natural products and drugs. In the last decade, significant advances have been made towards the asymmetric synthesis of 3-heteroatom-substituted oxindoles as a result of major improvements in asymmetric organocatalysis. This review will focus on the different types of asymmetric electrophilic organocatalyzed reactions, including the amination, halogenation, hydroxylation, and sulfenylation of oxindoles to form their enantioenriched 3-heterosubstituted derivatives.
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