期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 7, 页码 1256-1269出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800201
关键词
direct functionalization; early transition metals; lanthanides; metallacycles; synthetic methods
资金
- JSPS KAKENHI [JP26248028]
This review focuses on direct C-H bond functionalization reactions of N-heteroaromatic compounds by group 3 and 4 organometallic complexes. Early transition-metal-carbon and -nitrogen bonds are highly reactive to C-H bond activation via a sigma-bond metathesis pathway to form new organometallic species. By further inserting other unsaturated molecules into the new metal-carbon bond, C-H bond functionalized products are selectively obtained. To clarify the reaction mechanism, we categorize the reaction by the chelation size of the metallacycle intermediate generated from the organometallic species with N-heteroaromatic compounds, and include both stoichiometric and catalytic reactions with their reaction mechanism.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据