4.6 Article

In Situ Synthesis of WSe2/CMK-5 Nanocomposite for Rechargeable Lithium-Ion Batteries with a Long-Term Cycling Stability

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 4, 页码 4688-+

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03694

关键词

WSe2/CMK-5 nanocomposite; Anode; Lithium-ion batteries; Long-term cycling stability; Electrochemical property

资金

  1. National Natural Science Foundation of China [U1505241, 91433104, 51502036]

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Transition metal dichalcogenides (TMDs) have received intensive interests in lithium-ion batteries owing to their unique lithium-ion storage ability when evaluated as anode materials. In the present work, a nanocomposite of WSe2/CMK-5 was successfully fabricated via a nanocasting route, introducing the unique structure of mesoporous carbon (CMK-5) as a nanorecator. Benefiting from a synergetic effect of WSe2 nanosheets and mesoporous carbon, the WSe2/CMK-5 hybrid electrode exhibited large reversible capacity, high rate performance, and excellent long-term cycling stability. For instance, a specific capacity of 490 mA h g(-1) can remain even after 600 cycles at a current density of 0.5 A g(-1.)

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