期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 9, 页码 11555-11562出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b01738
关键词
Biogenic silica; Rice husk; Mechanochemistry; Iron oxide nanoparticles; Oxidations; Alkylations
资金
- MINECO [CTQ2016-78289-P, REF BES-2017-081560]
- FEDER
- Universidad de Cordoba through Programa Propio Galileo
- RUDN University Program 5-100
A template-free, simple, effective, and reproducible integrated mechanochemical/microwave promoted methodology has been designed to derive porous silica materials from rice husk waste. Microwave-assisted acid dissolution effectively removed metal ions from rice husk in order to obtain a highly pure (>95%) amorphous mesoporous silica with a surface area of 352 m(2) g(-1). As-synthesized silica materials were used as supports to prepare iron oxide-containing nanocatalyst via mechanochemistry employing a dry milling step in which the pore structure of silica was retained in the final materials after iron incorporation. Synthesized materials were characterized using different techniques including N-2 physisorption, powder X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and diffuse reflectance Fourier-transform infrared spectroscopy. Materials featured excellent and versatile catalytic activities in microwave-assisted oxidation and acid-catalyzed reactions. Toluene alkylation was successfully promoted in quantitative product yields with complete selectivity to monoalkylated products. The iron-containing catalyst exhibited good conversion (up to 44%) at complete benzaldehyde selectivity in the liquid-phase oxidation of benzyl alcohol.
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