期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 8, 页码 10806-10814出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b02112
关键词
Furfural; Biobased polymer; Poly(butylene succinate); Copolyester; Environmental biodegradability
资金
- JSPS KAKENHI [24710087]
- Precursory Research for Embryonic Science and Technology (PRESTO) program of the Japan Science and Technology Agency (JST) [JPMJPR13B7]
- Grants-in-Aid for Scientific Research [24710087] Funding Source: KAKEN
Furfural, a compound easily manufactured from hemicellulose on the global scale, has gained attention as a second-generation biomass resource. The synthesis of oxabicyclodicarboxylic anhydride (OBCA) from furfural alone and its polymerization with diol to form the biobased and biodegradable polyoxabicyclate (POBC) make OBCA a novel biobased monomer building block. To control the physical properties of POBC, we synthesized a copolyester of butanediol (BD), succinic anhydride (SAh), and OBCA. The structures of the resultant poly(butylene succinate-co-butylene oxabicyclate) (P(BS-co-BO)) polymers were studied using H-1 and C-13 NMR spectrometry, size-exclusion chromatography, thermal gravimetric analysis, differential scanning calorimetry, and wide-angle X-ray diffraction analysis. Physical properties of the melt-pressed films were examined by tensile strength testing, and the hydrolyzability of P(BS-co-BO)s was evaluated using a clear zone formation method with bacteria. To examine the environmental biodegradability of P(BS-co-BO), the biochemical oxygen demand for degrading their constituents was measured using the mixed inoculum method.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据