期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 8, 页码 9831-9844出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b00984
关键词
Furfural; Hydrogenation; Monometallic carbon-supported catalysts; Methylfuran; Batch; Continuous flow
资金
- European COST Action via Short Term Scientific Missions (STSMs) [FP1306]
- Universite de Technologie de Compiegne (France)
- Universidad de Cordoba (Spain)
- Aristotle University of Thessaloniki (Greece)
- China Scholarship Council
- RUDN University Program 5-100
This work compares the catalytic performance of well-defined monometallic catalysts supported on commercial microporous/mesoporous carbon (Cu/AC, Pd/AC, Pt/AC, and Ni/AC) for the liquid-phase hydrogenation of furfural, both in batch and in continuous flow. Whereas Ni/AC performed better in batch (in terms of selectivity to 2-methylfuran), better results were obtained with Pt/AC in continuous flow. Reutilization of the Ni/AC catalyst recovered by simple filtration after batch experiments changed the selectivity from 2-methylfuran to furfuryl alcohol. The solvent type and the reaction conditions were essential for the catalytic performance. Metal leaching was the main cause of catalyst deactivation.
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