期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 6, 期 7, 页码 8064-8092出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b00971
关键词
Biomass processing; Platform chemicals; HMF; BHMF; DFF; FDCA; Sustainable development; Organic synthesis
资金
- Russian Science Foundation (RSF) [17-13-01176]
- Russian Science Foundation [17-13-01176] Funding Source: Russian Science Foundation
Recent advances in the area of biomass-derived C6-furanic platform chemicals for sustainable biomass processing are analyzed focusing on chemical reactions important for development of practical applications and materials science. Among the chemical processes currently being studied, tuning the amount of oxygen-containing functional groups remains the most active research direction. Production of efficient fuels requires the removal of oxygen atoms (reduction reactions), whereas utilization of biomass derived furanic derivatives in material science points out the transformation importance of oxidation in order to form dicarboxylic derivatives. Stimulated by this driving force, oxidation and reduction of 5-(hydroxymethyl)furfural (HMF) are nowadays massively studied. Moreover, these fundamental transformations are often used as model reactions to test new catalysts, and HMF transformations guide the development of new catalytic systems. From the viewpoint of organic synthesis, highly diverse chemical reactivity is explored and a number of bioderived synthetic building blocks with different functional groups are now accessible. This Perspective covers the most recent literature (since Jan 2017) to highlight the emerging research trends.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据