期刊
INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE
卷 9, 期 4, 页码 510-517出版社
WILEY PERIODICALS, INC
DOI: 10.1111/ijag.12356
关键词
barium disilicate; crystal growth; crystallization; glass; Raman spectroscopy; silicate; structure; supercooled liquid
资金
- Sao Paulo Research Foundation [2016/18567-5, 2016/15962-0, 2013/07793-6]
- Federal Agency for the Support and Improvement of Higher Education (CAPES) [PNPD20131474, 33001014004P9]
- CNPq
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [16/15962-0] Funding Source: FAPESP
The homogeneous and stoichiometric crystallization of the barium disilicate (BaSi2O5) glass makes it possible to follow the structural evolution of Raman bands from the supercooled liquid to the crystalline phase. We monitored the crystallization of supercooled liquid BaSi2O5 at 790 degrees C over 440minutes revealing a three-stage crystallization process: stage 1 involves changes in the barium sites toward a bonding environment that is similar to that in orthorhombic low barium disilicate. The end of stage 1 is marked by the loss of the Q(4) species vibration at 1170cm(-1) and the creation of a crystalline band at 490cm(-1). Stage 2 is marked by the transition of the Q(3) peak (1060cm(-1)) from a Gaussian-like to a Lorentzian curve, indicating the formation of well-developed sheet structures. These observations lead us to conclude that the Raman spectra are resolving both the crystalline L-BS2 phase and the BS2 melt. The final stage involves a rapid decrease in the remaining Q(n) species to form Q(3). This crystallization process involves structural modifications that occur on the tens of microns scale. The barium cations drive the initial stages of crystallization, providing direct evidence that the short-range order, around network modifiers, is a critical factor involved in homogeneous crystallization.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据