期刊
SCIENTIFIC REPORTS
卷 8, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-018-24328-9
关键词
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资金
- JSPS KAKENHI [24880022, 16H06210]
- programme of RISH [M5-2-4]
- joint usage/research programme of IAE [ZE28A-32]
- CREST from Japan Science and Technology Agency [JPMJCR11B4]
- Grants-in-Aid for Scientific Research [16H06210, 24880022] Funding Source: KAKEN
Cross-linking between lignin and polysaccharide in plant cell-wall determines physical, chemical, and biological features of lignocellulosic biomass. Since Erdmann's first report in 1866, numerous studies have suggested the presence of a bond between hemicelluloses and lignin; however, no clear evidence for this interaction has been reported. We describe the first direct proof of covalent bonding between plant cell-wall polysaccharides and lignin. Nuclear magnetic resonance spectroscopy was used to observe the long-range correlations through an alpha-ether bond between lignin and the primary hydroxyl group of a mannose residue in glucomannan. Complete signal assignment of the cognate structural units was also achieved. Thus, we identified lignin-carbohydrate bonds by complete connectivity analysis from the phenylpropane unit to the carbohydrate moiety.
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