期刊
RSC ADVANCES
卷 8, 期 4, 页码 2132-2137出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra13245j
关键词
-
资金
- US Department of Energy [Office of Basic Energy Sciences] [DE-FG02-08ER 15997]
- Danish National Science Foundation through the Center for Carbon Dioxide Activation (CADIAC)
This paper describes the systematic study of metal-organic framework (MOF) catalysts for the reaction of propylene oxide (PO) with carbon dioxide (CO2) to generate propylene carbonate (PC). These studies began with the evaluation of MIL-101(Cr) as catalyst in a flow reactor. Under the developed flow conditions, MIL-101(Cr) was found to effectively catalyze PO carbonation in the absence of a halide co-catalyst. A systematic study of catalyst performance was then undertaken as a function of MOF synthesis technique, activation conditions, metal center, and node architecture. Ultimately, these investigations led to the identification of MIL-100(Sc) as a new, active, and stable catalyst for PO carbonation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据