期刊
RSC ADVANCES
卷 8, 期 4, 页码 2138-2147出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra09097h
关键词
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资金
- Priority Research Center Program through a National Research Foundation of Korea (NRF) grant - Ministry of Education, Science, and Technology [2009-0093819]
- National Research Foundation of Korea [2014-R1A1A4A03004026]
A novel three component (titanium dioxide nanowire (TiO2 NW), poly(3-aminophenyl boronic acid) (PAPBA) and gold nanoparticles (Au NPs)) based ternary nanocomposite (TNC) (designated as TiO2 NW/PAPBA-Au TNC) was prepared by a simple two-stage synthetic approach and utilized for the fabrication of a nonenzymatic (enzyme-free) glucose (NEG) sensor. In stage 2, the PAPBA-Au NC was formed by oxidative polymerization of 3-APBA using HAuCl4 as oxidant on the surface of pre-synthesized TiO2 NW via electrospinning (stage 1). The formation of PAPBA-Au NC as the shell on the surface of the TiO2 NW (core) was confirmed by field emission scanning electron microscopy (FE-SEM). Notably, we obtained a good peak to peak separation, and a high peak current for the redox Fe(CN)(6)(3-/4-) process indicating excellent electron transfer capability at the glassy carbon electrode (GCE)/TiO2 NW/PAPBA-Au TNC interface. Also, the fabricated TiO2 NW/PAPBA-Au TNC provides excellent electrocatalytic activity towards glucose detection in neutral (pH = 7.0) phosphate buffer solution. The detection of glucose was monitored using differential pulse voltammetry. The obtained sensitivity and detection limits are superior to many of the TiO2 based enzymatic and non-enzymatic glucose sensors reported in the literature. Furthermore, the TiO2 NW/PAPBA-Au TNC sensor is preferred because of its high selectivity to glucose in the presence of co-existing interfering substances and practical application for monitoring glucose in human blood serum samples.
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