期刊
RSC ADVANCES
卷 8, 期 12, 页码 6690-6698出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra00792f
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资金
- Office of the Vice President for Research at the University of South Carolina
- University of South Carolina Aiken
Salts of the diazonium coupling agent p-phenylenebis(diazonium) form diazonium-terminated conjugated thin films on a variety of conductive and nonconductive surfaces by spontaneous reaction of the coupling agent with the surface. The resulting diazonium-bearing surface can be reacted with various organic and inorganic nucleophiles to form a functionalized surface. These surfaces have been characterized with voltammetry, XPS, infrared and Raman spectroscopy, and atomic force microscopy. Substrates that can be conveniently and quickly modified with this process include ordinary glass, gold, and an intact, fully assembled commercial screen-printed carbon electrode. The scope and convenience of this process make it promising for practical surface modification.
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