期刊
RSC ADVANCES
卷 8, 期 3, 页码 1583-1592出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra11676d
关键词
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资金
- National Natural Science Foundation of China [21407154, 21507137]
- West Light Foundation of The Chinese Academy of Sciences
Cu-Ce/graphene catalysts show high dispersion of metal particles and excellent activity and stability for catalytic oxidation. In this study, a hydrothermal method was used to synthesize a series of bimetallic Cu-Ce/graphene catalysts, and the effects of the proportions of Cu and Ce on CO oxidation were investigated in detail. Indispensable characterizations such as XPS, XRD, TEM, BET, and H-2-TPR were conducted to explore the effect of the Cu/Ce molar ratio and the metal valence on the activity and determine the structure-performance relationship. The results showed that bimetallic supported catalysts, such as 3Cu5Ce/graphene, 1Cu1Ce/graphene, and 5Cu3Ce/graphene, possessed significant catalytic activity. Especially, the 5Cu3Ce/graphene catalyst showed highest catalytic activity for CO oxidation, the T-100 value was 132 degrees C, and the apparent activation energy was 68.03 kJ mol(-1). Furthermore, the stability of the 5Cu3Ce/graphene catalyst was outstanding, which could be maintained for at least 12 h. Moreover, the CeO2 particles were well crystalline with the size 5-9 nm in these catalysts, and the CuO nanoparticles were well dispersed on CeO2 and graphene. Notably, the ratio of Cu/Ce in the catalyst was higher, the interaction between the Ce species and the graphene was stronger, and the Cu species were more easily reduced; this was beneficial for the oxidation of CO.
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