期刊
RSC ADVANCES
卷 8, 期 5, 页码 2575-2585出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra12816a
关键词
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资金
- Anhui Provincial Natural Science Foundation [1708085ME113]
- National Key Technology RD Program [2013BAJ01B05]
A material (ZIF-8@SiO2) with a nuclear shell structure was synthesized to improve the flame retardancy and smoke suppression of epoxy resin (EP) through a synergetic catalytic effect. Zeolitic imidazolate framework-8 (ZIF-8) was synthesized and its surface was coated with SiO2 by hydrolyzing tetraethyl orthosilicate. Core-shell structured ZIF-8@SiO2 was obtained. Then ZIF-8@SiO2 was added to EP to explore its effect of flame retardancy and smoke suppression on the EP composite. The results of a cone calorimeter test showed that the peak heat release rate, total heat release, smoke production rate and total smoke production of the material were decreased by 75.9%, 38.9%, 51.1% and 39.8%, respectively, after 2 wt% ZIF-8@SiO2 was added to EP. Besides, through the analysis of char residue, the mechanism of ZIF-8@SiO2/EP's flame retardancy and smoke suppression was determined to be due to the physical barrier effect of SiO2 and the co-effect of SiO2 and ZnO decomposition by ZIF-8.
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