期刊
RSC ADVANCES
卷 8, 期 27, 页码 14829-14832出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra02224k
关键词
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资金
- National Natural Science Foundation of China [21202092]
- China Three Gorges University [KJ2014B084, KJ2014H008]
A practical one-pot synthesis of chiral alcohols from readily available alkynes via tandem catalysis by the combination of CF3SO3H and a fluorinated chiral diamine Ru(ii) complex in aqueous CF3CH2OH is described. Very interestingly, the combination of fluorinated catalysts and solvent exhibits a positive fluorine effect on the reactivity and enantioselectivity. A range of chiral alcohols with wide functional group tolerance was obtained in high yield and excellent stereoselectivity under simple and mild conditions.
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