期刊
JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE
卷 56, 期 3, 页码 348-356出版社
KOREAN CHEMICAL SOC
DOI: 10.5012/jkcs.2012.56.3.348
关键词
Bisazo pyrazolin-5-ones; Azo-hydrazone tautomerism; Fastness properties; CIELAB coordinates
资金
- Academy of Scientific Research and Technology, ASRT, Egypt, Grant
In an attempt to find a new class of bisazo disperse dyes with better dyeing properties, a series of novel bisazo dyestuffs based on 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones 3a-f were prepared by diazocoupling of p-nitrophenyl diazonium chloride with 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones 2a-f. Compounds 3a-f were subsequently reacted with acetic anhydride in the presence of p-toluenesulfonic acid afford the corresponding O-acetyl derivatives 4a-f. The latter products as well as spectral data indicated that compounds 3a-f exist predominantly in the azo-hydrazone tautomeric form (H) as the ZE-configuration. Additionally, two series of the synthesized dyes 3a-f and 4a-f were applied as disperse dyes for dyeing polyester fabrics and their fastness properties were evaluated. Also the position of color in CIELAB coordinates (L*, a*, b*, H*, C*) was assessed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据