期刊
MATERIALS
卷 11, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/ma11071124
关键词
Ni-Co-Y2O3 composite; chronoamperometry; instantaneous nucleation; kinetic parameters
类别
资金
- National Natural Science Foundation of China [51674141]
Ni-Co alloy and Ni-Co-Y2O3 multiple coatings refined with nano-Y2O3 particles were fabricated by ultrasonic-assisted electrochemical deposition in an acid sulfamate bath. Linear sweep voltammetry (LSV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) techniques were applied to investigate the nucleation/growth process of composite coatings in co-deposition. The LSV results indicated that the incorporation of nano-Y(2)O(3 )particles with the Ni-Co matrix shifted the initial deposition potential to a more positive potential and decreased cathodic polarization. For both coatings, the nucleation/growth process approximately agreed with the Scharifker-Hill instantaneous nucleation model. Nucleation parameters, including active nucleation sites (N-0) and nucleation rate (A) of the composite, were higher when the measured potential range was between -1.05 V (vs. SCE) and -1.20 V vs. SCE, when compared with the Ni-Co alloy, and the observed AFM images of the coatings were in good agreement with the calculated nucleation parameters (using the Marquardt-Levenberg algorithm) of experimental curves. EIS testing indicated that the charge transfer resistance of the composite was lower in electrodeposition. The incorporation of nano-Y2O3 particles in the matrix changed the preferred orientation of coatings and produced a more uniform and compact deposit layer with finer grains.
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