期刊
GREEN CHEMISTRY LETTERS AND REVIEWS
卷 11, 期 2, 页码 158-164出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/17518253.2018.1444794
关键词
Benzene; methanol alkylation; toluene; Lewis; Bronsted acid; coke
资金
- science and technology support project of Gansu Province [1604GKCD026, 2016GS09293]
The secondary reaction of toluene is difficult to be suppressed in benzene alkylation with methanol over conventional acidic zeolite catalysts. Moreover, the formation of coke yet remains a challenging problem. In this study, Na-Y zeolites were modified with ammonium carbonate (AC), citric acid (CA) and caesium nitrate(CN) to evaluate the alkylation of benzene with methanol, which was also characterized by XRD, SEM, FT-IR, N-2 adsorption and Py-IR. For the Na-Y treated with AC-CA-CN, not only the catalytic selectivity for the alkylation of benzene with methanol was improved (the total selectivity of toluene and xylene was 97.9% and toluene selectivity was 86.4%), but also the quantity of coke was greatly decreased. [GRAPHICS] .
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