期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 8, 期 11, 页码 2779-2783出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cy00681d
关键词
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资金
- European Research Council [ERC CoG 615653]
- Swiss National Science Foundation [200021_162868, 206021_170755]
- Irish Research Council
- Swiss National Science Foundation (SNF) [206021_170755, 200021_162868] Funding Source: Swiss National Science Foundation (SNF)
NHC iron(ii) piano-stool complexes catalyse the selective semi-hydrogenation of alkynes to alkenes using silanes as reducing agents. Aromatic terminal alkynes are converted to styrenes without over-reduction to ethylbenzene derivatives. Furthermore, internal aryl alkynes afford cis-alkenes with excellent Z-selectivity.
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